Fusion and State Equation of Simple Liquids. I. Derivation of the Expressions for State Equation and Free Energy
نویسندگان
چکیده
منابع مشابه
DERIVING THE EQUATION OF STATE FOR LIQUIDS AND EXTENSION OF THE PRINCIPLE OF CORRESPONDING STATES
A new simple model is introduced for a liquid and an equation of state is derived based on this model and the statistical mechanical calculations. This equation of state works well for the non-polar and slightly polar liquids. The important conclusion that may be deduced from this equation of state is that if the reduced variables of state are chosen and defined appropriately, then, the pri...
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An analytical equation of state by Song and Mason is developed to calculate the PVT properties ofmercury. The equation of state is based on the statistical-mechanical perturbation theory of hard convexbodies and can be written as a fifth-order polynomial in the density. There exists three temperaturedependentparameters in the equation of state; the second virial coefficient, an effective molecu...
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An analytical equation of state was applied to calculate the thermodynamic properties for argon.The equation of state is that of Song and Mason. It is based on a statistical-mechanical perturbationtheory of the hard convex bodies and can be written as fifth-order polynomial in the density. Thereexist three temperature-dependent parameters: the second virial coefficient, an effective molecularvo...
متن کاملderiving the equation of state for liquids and extension of the principle of corresponding states
a new simple model is introduced for a liquid and an equation of state is derived based on this model and the statistical mechanical calculations. this equation of state works well for the non-polar and slightly polar liquids. the important conclusion that may be deduced from this equation of state is that if the reduced variables of state are chosen and defined appropriately, then, the princip...
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1950
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.23.236